Q1: What are the typical applications of 1,2-Bis(2-chloroethoxy)ethane in polymer chemistry?
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A1: this compound serves as a valuable monomer in synthesizing polymers with diverse properties. For instance, it acts as a building block in creating poly(ethylene oxide-co-ethylene sulfide)s []. These polymers are further oxidized to produce poly(ethylene oxide-co-ethylene sulfone)s. The resulting polymers exhibit a range of glass transition temperatures, melting points, and solubilities based on the ratio of ether oxygen to sulfur. This tunability makes them suitable for various applications.
Q2: Can you elaborate on the role of this compound in synthesizing macrocycles?
A2: this compound plays a crucial role in constructing the fourteen-membered ring of 7,7,12,12-tetramethyl-1,4-dioxacyclotetradecane-8,9,10,11-tetrone []. It provides the central ethylene glycol unit that bridges two isobutyric acid-derived units connected via an acetylene bridge. This synthesis highlights the versatility of this compound in building complex molecular architectures.
Q3: How does this compound contribute to research in photocatalysis?
A3: While not directly involved in photocatalysis, this compound serves as a model substrate for evaluating the photocatalytic activity of titanium dioxide (TiO2) []. Researchers investigate the degradation of this compound in the presence of TiO2 under UV irradiation to assess the efficiency of different TiO2 recovery and sedimentation methods. This information helps optimize TiO2 reusability in suspended photocatalyst reactors.
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Q4: Are there any notable structural features of compounds derived from this compound?
A4: Research shows that macrocycles synthesized using this compound, like 7,7,12,12-tetramethyl-1,4-dioxacyclotetradecane-8,9,10,11-tetrone, exhibit intriguing structural features []. X-ray crystallography and computational studies revealed a transannular interaction between the dioxaethane bridge (derived from this compound) and the dicarbonyl moiety within the macrocycle. This interaction influences the compound's electrochemical and spectroscopic properties.
1,2-Bis(2-chloroethoxy)ethane is used as pharmaceutical intermediate.
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Applications
1,2-Bis(2-chloroethoxy)ethane is used as pharmaceutical intermediate.
Solubility
Insoluble in water.
Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents.