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Ammonium sulfate (American English and international scientific usage; ammonium sulphate in British English); (NH4)2SO4, is an inorganic salt with a number of commercial uses. The most common use is as a soil fertilizer. It contains 21% nitrogen and 24% sulfur.
Uses
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The primary use of ammonium sulfate is as a fertilizer for alkaline soils. In the soil, the ammonium ion is released and forms a small amount of acid, lowering the pH balance of the soil, while contributing essential nitrogen for plant growth. The main disadvantage to the use of ammonium sulfate is its low nitrogen content relative to ammonium nitrate, which elevates transportation costs.[2]
It is also used as an agricultural spray adjuvant for water-soluble insecticides, herbicides, and fungicides. There, it functions to bind iron and calcium cations that are present in both well water and plant cells. It is particularly effective as an adjuvant for 2,4-D (amine), glyphosate, and glufosinate herbicides.
Laboratory use
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Ammonium sulfate precipitation is a common method for protein purification by precipitation. As the ionic strength of a solution increases, the solubility of proteins in that solution decreases. Ammonium sulfate is extremely soluble in water due to its ionic nature, therefore it can "salt out" proteins by precipitation.[3] Due to the high dielectric constant of water, the dissociated salt ions being cationic ammonium and anionic sulfate are readily solvated within hydration shells of water molecules. The significance of this substance in the purification of compounds stems from its ability to become more so hydrated compared to relatively more nonpolar molecules and so the desirable nonpolar molecules coalesce and precipitate out of the solution in a concentrated form. This method is called salting out and necessitates the use of high salt concentrations that can reliably dissolve in the aqueous mixture. The percentage of the salt used is in comparison to the maximal concentration of the salt in the mixture can dissolve. As such, although high concentrations are needed for the method to work adding an abundance of the salt, over 100%, can also oversaturate the solution, therefore, contaminating the nonpolar precipitate with salt precipitate.[4] A high salt concentration, which can be achieved by adding or increasing the concentration of ammonium sulfate in a solution, enables protein separation based on a decrease in protein solubility; this separation may be achieved by centrifugation. Precipitation by ammonium sulfate is a result of a reduction in solubility rather than protein denaturation, thus the precipitated protein can be solubilized through the use of standard buffers.[5] Ammonium sulfate precipitation provides a convenient and simple means to fractionate complex protein mixtures.[6]
In the analysis of rubber lattices, volatile fatty acids are analyzed by precipitating rubber with a 35% ammonium sulfate solution, which leaves a clear liquid from which volatile fatty acids are regenerated with sulfuric acid and then distilled with steam. Selective precipitation with ammonium sulfate, opposite to the usual precipitation technique which uses acetic acid, does not interfere with the determination of volatile fatty acids.[7]
Food additive
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As a food additive, ammonium sulfate is considered generally recognized as safe (GRAS) by the U.S. Food and Drug Administration,[8] and in the European Union it is designated by the E number E517. It is used as an acidity regulator in flours and breads.[9][10][11]
Other uses
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In the treatment of drinking water, ammonium sulfate is used in combination with chlorine to generate monochloramine for disinfection.[12]
Ammonium sulfate is used on a small scale in the preparation of other ammonium salts, especially ammonium persulfate.
Ammonium sulfate is listed as an ingredient for many United States vaccines per the Centers for Disease Control.[13]
A saturated solution of ammonium sulfate in heavy water (D2O) is used as an external standard in sulfur (33S) NMR spectroscopy with shift value of δ = 0 ppm.
Ammonium sulfate has also been used in flame retardant compositions acting much like diammonium phosphate. As a flame retardant, it increases the combustion temperature of the material, decreases maximum weight loss rates, and causes an increase in the production of residue or char.[14] Its flame retardant efficacy can be enhanced by blending it with ammonium sulfamate.[citation needed] It has been used in aerial firefighting.
Ammonium sulfate has been used as a wood preservative, but due to its hygroscopic nature, this use has been largely discontinued because of associated problems with metal fastener corrosion, dimensional instability, and finish failures.
Preparation
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Ammonium sulfate is made by treating ammonia with sulfuric acid:
2 NH3 + H2SO4 &#; (NH4)2SO4
A mixture of ammonia gas and water vapor is introduced into a reactor that contains a saturated solution of ammonium sulfate and about 2% to 4% of free sulfuric acid at 60 °C. Concentrated sulfuric acid is added to keep the solution acidic, and to retain its level of free acid. The heat of reaction keeps reactor temperature at 60 °C. Dry, powdered ammonium sulfate may be formed by spraying sulfuric acid into a reaction chamber filled with ammonia gas. The heat of reaction evaporates all water present in the system, forming a powdery salt. Approximately 6,000 million tons were produced in .[2]
Ammonium sulfate also is manufactured from gypsum (CaSO4·2H2O). Finely divided gypsum is added to an ammonium carbonate solution. Calcium carbonate precipitates as a solid, leaving ammonium sulfate in the solution.
(NH4)2CO3 + CaSO4 &#; (NH4)2SO4 + CaCO3
Ammonium sulfate occurs naturally as the rare mineral mascagnite in volcanic fumaroles and due to coal fires on some dumps.[15]
Properties
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Ammonium sulfate becomes ferroelectric at temperatures below &#;49.5 °C. At room temperature it crystallises in the orthorhombic system, with cell sizes of a = 7.729 Å, b = 10.560 Å, c = 5.951 Å. When chilled into the ferrorelectric state, the symmetry of the crystal changes to space group Pna21.[16]
Reactions
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Ammonium sulfate decomposes upon heating above 250 °C (482 °F), first forming ammonium bisulfate. Heating at higher temperatures results in decomposition into ammonia, nitrogen, sulfur dioxide, and water.[17]
As a salt of a strong acid (H2SO4) and weak base (NH3), its solution is acidic; the pH of 0.1 M solution is 5.5. In aqueous solution the reactions are those of NH+
4 and SO2&#;
4 ions. For example, addition of barium chloride, precipitates out barium sulfate. The filtrate on evaporation yields ammonium chloride.
Ammonium sulfate forms many double salts (ammonium metal sulfates) when its solution is mixed with equimolar solutions of metal sulfates and the solution is slowly evaporated. With trivalent metal ions, alums such as ferric ammonium sulfate are formed. Double metal sulfates include ammonium cobaltous sulfate, ferrous diammonium sulfate, ammonium nickel sulfate which are known as Tutton's salts and ammonium ceric sulfate.[2] Anhydrous double sulfates of ammonium also occur in the Langbeinites family. The ammonia produced has a pungent smell and is toxic.
Airborne particles of evaporated ammonium sulfate comprise approximately 30% of fine particulate pollution worldwide.[18]
Legislation and control
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In November , a ban on ammonium sulfate, ammonium nitrate and calcium ammonium nitrate fertilizers was imposed in the former Malakand Division&#;comprising the Upper Dir, Lower Dir, Swat, Chitral and Malakand districts of the North West Frontier Province (NWFP) of Pakistan, by the NWFP government, following reports that they were used by militants to make explosives. In January , these substances were also banned in Afghanistan for the same reason.[19]
See also
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References
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Further reading
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Ammonium sulfate [(NH&#;)&#; SO&#;] was one of the first and most widely used nitrogen (N) fertilizers for crop production. It&#;s now less common but especially valuable where both N and sulfur (S) are required. Its high solubility provides versatility for a number of agricultural applications.
Production
Ammonium sulfate (sometimes abbreviated as AS or AMS) has been produced for more than 150 years. Initially, it was made from ammonia released during manufacturing coal gas (used to illuminate cities) or from coal coke used to produce steel.
Today, manufacturers make ammonium sulfate by reacting sulfuric acid with heated ammonia. To get the crystal size best suited for the application, reaction conditions are controlled by screening and drying the particles until achieving the desired size. Some materials are coated with a conditioner to reduce dust and caking.
Byproducts from various industries meet most of the current demand for ammonium sulfate. For example, the nylon manufacturing process produces ammonium sulfate as a co-product. In another, certain byproducts that contain ammonia or spent sulfuric acid are commonly converted to ammonium sulfate for use in agriculture.
Although the color can range from white to beige, ammonium sulfate is consistently sold as a highly soluble crystal with excellent storage properties. As described earlier, particle size can also vary depending on the intended purpose.
Chemical properties
Agricultural use
Growers apply ammonium sulfate primarily where they need supplemental N and S to meet the nutritional requirement of growing plants. Since ammonium sulfate contains only 21 percent N, other fertilizer sources more concentrated and economical to handle and transport often make a better choice for N-deficient fields. It provides an excellent source of S, which supports or drives numerous essential plant functions, including protein synthesis.
Because the N fraction is present in the ammonium form of ammonium sulfate, rice farmers frequently apply it to flooded soils, since nitrate-based fertilizers are a poor choice due to denitrification losses.
A solution containing dissolved ammonium sulfate is often added to post-emergence herbicide sprays to improve their effectiveness at weed control.
This practice of increasing herbicide efficacy with ammonium sulfate works particularly well when the water supply contains significant concentrations of calcium (Ca), magnesium (Mg) or sodium (Na). A high-purity grade of ammonium sulfate often works best for this purpose to avoid plugging spray nozzles.
Management practices
After addition to soil, the ammonium sulfate rapidly dissolves into its ammonium and sulfate components. If it remains on the soil surface, the ammonium may be susceptible to gaseous loss in alkaline conditions. In these situations, agronomists advise incorporating the material into the soil as soon as possible. Other options include an ammonium sulfate application before irrigation or a predicted rainfall.
Most plants can utilize both ammonium and nitrate forms of N for growth. In warm soils, microbes will rapidly begin to convert ammonium to nitrate in the process of nitrification [2 NH&#;&#; + 3O&#; &#; 2NO&#;&#; + 2H&#;O + 4H&#;]. During this microbial reaction, acidity [H&#;] is released, which will ultimately decrease soil pH after repeated use.
Ammonium sulfate has an acidifying effect on soil due to the nitrification process, not from the presence of sulfate, which has a negligible effect on pH.
The acid-producing potential of ammonium sulfate is greater than the same N application from ammonium nitrate, for example. That&#;s because all of the N in ammonium sulfate converts to nitrate, compared with only half of the N from ammonium nitrate that converts to nitrate.
Non-agricultural uses
Source: Nutrient Source Specifics, No. 12, International Plant Nutrition Institute.
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